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Zero-field splittings of the ligand localized 3ππ* phosphorescence of the Ru(II) complex with the π-conjugated ligand

✍ Scribed by Hisayuki Miki; Seiya Kimachi; Rei Satomi; Tohru Azumi; Masayoshi Onishi

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 373 KB
Volume: 218
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00038-7

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✦ Synopsis

The phosphorescence of [ Ru (bhq) (CO )sCI (L) ] (L = PEts, p-toluidine and piperidine ) in glassy rigid solution and in crystals are observed. We have further obtained zero-field splittings by the method of optical detection of magnetic resonance. The location of the spectrum, lifetime, and the zero-field splittings all indicate that the emission is from the ligand localized 3rt~* state.

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