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Zero-field splittings of phenanthroline-localized 3ππ* emitting levels in mixed-ligand zinc(II) complexes

✍ Scribed by Seiichi Yamamoto; Shigeru Ikeda; Takeshi Ikeyama; Tohru Azumi; G.A. Crosby

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
230 KB
Volume
174
Category
Article
ISSN
0009-2614

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Zero-field splittings of the ligand loca
Zero-field splittings of the ligand localized 3ππ* phosphorescence of the Ru(II) complex with the π-conjugated ligand
✍ Hisayuki Miki; Seiya Kimachi; Rei Satomi; Tohru Azumi; Masayoshi Onishi 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 373 KB

The phosphorescence of [ Ru (bhq) (CO )sCI (L) ] (L = PEts, p-toluidine and piperidine ) in glassy rigid solution and in crystals are observed. We have further obtained zero-field splittings by the method of optical detection of magnetic resonance. The location of the spectrum, lifetime, and the zer