Formation of 18e− and 16e− Acyl(η3-cyclo
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Rachad El Mail; María A. Garralda; Ricardo Hernández; Lourdes Ibarlucea; Elena P
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Article
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2002
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John Wiley and Sons
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German
⚖ 137 KB
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The reaction of cationic diolefinic rhodium(I) complexes with 2-(diphenylphosphino)benzaldehyde (pCHO) was studied. [Rh(cod) 2 ]ClO 4 (cod cycloocta-1,5-diene) reacted with pCHO to undergo the oxidative addition of one pCHO with (1,2,3-h)cyclooct-2-en-1-yl (h 3 -C 8 H 13 ) formation, and the coordin