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Xenon trioxide oxidation of certain alcohols

โœ Scribed by Harold J. Rhodes; Martin I. Blake

Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
310 KB
Volume
56
Category
Article
ISSN
0022-3549

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โœฆ Synopsis

A series of alcohols, aliphatic and aromatic, was oxidized with xenon trioxide.

Oxidation to carbon dioxide and water was effected by adding a known excess of xenon trioxide to the reaction mixture. T h e excess reagent was determined iodometrically. Of the alcohols tested only triphenylcarbinol resisted oxidation. Essentially quantitative recoveries were obtained for ethanol, normal, secondary, and tertiary butyl alcohols, benzyl alcohol, benzohydrol, and cinnamyl alcohol.

HB PREPARATION and oxidizing properties of

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