A series of alcohols, aliphatic and aromatic, was oxidized with xenon trioxide. Oxidation to carbon dioxide and water was effected by adding a known excess of xenon trioxide to the reaction mixture. T h e excess reagent was determined iodometrically. Of the alcohols tested only triphenylcarbinol re
Xenon trioxide oxidation of certain alcohols
โ Scribed by Harold J. Rhodes; Martin I. Blake
- Publisher
- John Wiley and Sons
- Year
- 1967
- Tongue
- English
- Weight
- 310 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3549
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๐ SIMILAR VOLUMES
Benzyl alcohol is oxidized by xenon trioxide in acidic or neutral solution to benzaldehyde and benzoic acid. T h e course of the reaction was followed by gas chromatography. Thin-layer chromatography was used to identify the products of oxidation.
A gas chromatographic method has been developed for the determination of caffeine in plasma. A standard response curve relating signal-height ratios of caffeine to hexobarbital permits a quantitative estimation of the amount of caffeine present. The method is more rapid and sensitive than any previo
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