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Selective Oxidation of Primary and Secondary Alcohols with Chromium Trioxide in Ionic Liquid.

โœ Scribed by Yun-Fa Zheng; Xing-Fen Du; Wei-Liang Bao


Publisher
John Wiley and Sons
Year
2006
Weight
14 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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Kinetics and mechanism of cerium(IV) oxi
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The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 ยฐC. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation