X-ray photoelectron spectra of ylide—TCNQ charge-transfer complexes
✍ Scribed by Shinji Tsuchiya; Manabu Senō
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 205 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The amount of charge transfer in TTF-TCNQ and related solid compleses was determined by the anzdysis of the S 2p peak shape in their X-ray photoelectron spectra. The amount of charge transfer is 0.56 i 0.05 in TTF-TCNQ. The molccular ratio of TTF+ in the TTF column is determined to be 0.71 i 0.05 in
Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' \_ This