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Charge transfer shake-up satellites in X-ray photoelectron spectra of solid compounds of 3d0 ions

✍ Scribed by D.C. Frost; C.A. McDowell; B. Wallbank

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 395 KB
Volume: 40
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85056-7

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✦ Synopsis

Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' _ This is the first observation of satellites which are probably due to tzg -+ t& monopole charge transfer transitions. The probability for this transition is usually low, resulting in the observation of satellites due to the eg -c eg transition.

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