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X-ray crystal structure of cis-mini-3 (a spiralene[3])

✍ Scribed by J.R. Thiel; Charles J. Simmons; Robert S.H. Liu


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
131 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The X-ray crystal structure of the highly crowded c.is isomer of the lowest member of the homologs of [~-carotene has been determined at 120K. The triene chromophore exists in the postulated bis-S-cis conformation, assuming the novel spiral shape suitable for secondary 1,6-orbital interaction.


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## Abstract Hydrolysis of 2‐methylthiazolo[5,4‐__b__]pyridine resulted in ring opening of the thiazole and formation of 3‐acetamido‐2(1__H__)‐pyridinethione whose X‐ray crystal structure has been determined.