𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hydrolysis of methylthiazolopyridines. X-ray crystal structure of 3-acetamido-2(1H)-pyridinethione

✍ Scribed by Gianluca Giorgi; Laura Salvini; Fabio Ponticelli

Publisher
Journal of Heterocyclic Chemistry
Year
2000
Tongue
English
Weight
204 KB
Volume
37
Category
Article
ISSN
0022-152X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Hydrolysis of 2‐methylthiazolo[5,4‐b]pyridine resulted in ring opening of the thiazole and formation of 3‐acetamido‐2(1__H__)‐pyridinethione whose X‐ray crystal structure has been determined.

📜 SIMILAR VOLUMES

Pyridinethiones, X Preparation of Penten
Pyridinethiones, X Preparation of Pentene-1,5-dione Enolates and of 3-Benzoyl-2(1H)-Pyridinethiones
✍ Becher, Jan ;Asaad, Fahmy M. ;Winckelmann, Ib 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 401 KB

## Abstract An effective synthesis of 3‐benzoyl‐2(1 __H__)‐pyridinethiones **5a** – **n** from stable enol salts **4** of pentene‐1,5‐diones and isothiocyanates is described. An attempt to prepare a 3‐acetyl‐2(1 __H__)‐pyridinethione from the cyano compound **7** and CH~3~MgX yielded the ketimine *

Preparation and Reductive Decomposition
Preparation and Reductive Decomposition of 2-Iodoxybenzenesulfonic Acid. X-ray Crystal Structure of 1-Hydroxy-1H-1,2,3-benziodoxathiole 3,3-Dioxide
✍ Alexey Y. Koposov; Dmitry N. Litvinov; Viktor V. Zhdankin; Michael J. Ferguson; 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 118 KB 👁 1 views

## Abstract 2‐Iodoxybenzenesulfonic acid (in a cyclic tautomeric form of 1‐hydroxy‐1__H__‐1,2,3‐benziodoxathiole 1,3,3‐trioxide), a thia‐analog of 2‐iodoxybenzoic acid (IBX) and a potentially important oxidizing reagent, was prepared by two different pathways: direct oxidation of 2‐iodobenzenesulfo