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Wide-line 2H n.m.r. study of perdeuterated pyridine imbibed in a premium coal

โœ Scribed by Antoni Jurkiewicz; James S. Frye; Gary E. Maciel


Book ID
107756476
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
418 KB
Volume
69
Category
Article
ISSN
0016-2361

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Wide line N.M.R. spectra have been recorded from 90'K for the three dioxonium + salts : n50\*+c104 ; H502+Br and 502 SbC16 . From a second moment analysis in the rigid lattice, external hydrogen bonds are found significantly bent with dOH = 0.991 i for the bromide and 1.009 i for the perchlorate.

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## Abstract Seven isomeric 4,5,6โ€trimethylโ€2โ€oxoโ€1,3,2โ€dioxathians, __cis__โ€4โ€__trans__โ€6โ€dimethylโ€__r__โ€2โ€oxoโ€1,3,2โ€dioxathian and two isomeric 4,5,5,6โ€tetramethylโ€2โ€oxoโ€1,3,2โ€dioxathians were prepared and their ^1^H n.m.r. spectra analysed. The values of the vicinal coupling constants reported ea