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Wide line N.M.R. study of the proton hydrates in crystallized salts : III- di-aquooxonium ion

โœ Scribed by M.H. Herzog-Cance; J. Potier; A. Potier

Book ID
103896644
Publisher
Elsevier Science
Year
1981
Weight
984 KB
Volume
20
Category
Article
ISSN
0378-4487

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Wide line N.M.R. study of the proton hyd
Wide line N.M.R. study of the proton hydrates in crystallized salts : II dioxonium ion
โœ M.H. Herzog-Cance; J. Potier; A. Potier ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science โš– 923 KB

Wide line N.M.R. spectra have been recorded from 90'K for the three dioxonium + salts : n50\*+c104 ; H502+Br and 502 SbC16 . From a second moment analysis in the rigid lattice, external hydrogen bonds are found significantly bent with dOH = 0.991 i for the bromide and 1.009 i for the perchlorate.