Well-Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient Hydrosilylation of Amides to Amines and Nitriles
✍ Scribed by David Bézier; Dr. Gopaladasu T. Venkanna; Dr. Jean-Baptiste Sortais; Prof. Dr. Christophe Darcel
- Book ID
- 112019166
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 224 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1867-3880
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📜 SIMILAR VOLUMES
A general and efficient hydrosilylation of aldehydes and ketones into the corresponding alcohols using the well-defined bis(diphenylphosphino-A C H T U N G T R E N N U N G ethane)iron dihydride complex as the pre-catalyst is reported using polymethylhydrosiloxane (PMHS) as the reducing silylating ag
## Abstract A comparative study on the catalytic activity of a series of [IrCl~2~Cp\*(NHC)] complexes in several C–O and C–N coupling processes implying hydrogen‐borrowing mechanisms has been performed. The compound [IrCl~2~Cp\*(I^__n__Bu^)] (Cp\*=pentamethyl cyclopentadiene; I^__n__Bu^=1,3‐di‐__n_
## Abstract After subsequent desilylation a wide range of primary and secondary alcohols is available in good to high yields.