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ChemInform Abstract: Iron Dihydride Complex as the Pre-Catalyst for Efficient Hydrosilylation of Aldehydes and Ketones under Visible Light Activation.

✍ Scribed by Luis C. Misal Castro; David Bezier; Jean-Baptiste Sortais; Christophe Darcel

Book ID: 102063981
Publisher: John Wiley and Sons
Year: 2011
Weight: 46 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201139031

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✦ Synopsis

Abstract

After subsequent desilylation a wide range of primary and secondary alcohols is available in good to high yields.

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A general and efficient hydrosilylation of aldehydes and ketones into the corresponding alcohols using the well-defined bis(diphenylphosphino-A C H T U N G T R E N N U N G ethane)iron dihydride complex as the pre-catalyst is reported using polymethylhydrosiloxane (PMHS) as the reducing silylating ag

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