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Well-controlled ring-opening polymerization of cyclic esters catalyzed by aluminum amido complexes: Kinetics and mechanism

โœ Scribed by Liu, Junpeng; Ma, Haiyan

Book ID
126206236
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
595 KB
Volume
52
Category
Article
ISSN
0887-624X

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Ring-opening polymerization of six-membe
Ring-opening polymerization of six-membered cyclic esters catalyzed by tetrahydroborate complexes of rare earth metals
โœ Yuushou Nakayama; Kenta Sasaki; Naoki Watanabe; Zhengguo Cai; Takeshi Shiono ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 341 KB

Catalytic behavior of tetrahydroborate complexes of rare earth metals, Ln(BH 4 ) 3 (THF) x (1: ), for ring-opening polymerization (ROP) of six-membered cyclic esters, d-valerolactone (VL) and D,L-lactide (D,L-LA), was studied. The controlled polymerization of VL with 1-6 proceeded in THF at 60 C. T