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Ring-opening polymerization of cyclic esters initiated by zirconium, titanium and yttrium complexes

✍ Scribed by Tsai, Chen-Yen; Du, Hong-Cyuan; Chang, Jen-Chieh; Huang, Bor-Hunn; Ko, Bao-Tsan; Lin, Chu-Chieh

Book ID
127394729
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
790 KB
Volume
4
Category
Article
ISSN
2046-2069

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## Abstract **Summary:** The Ti^III^Cp~2~Cl‐catalyzed radical ring opening of epoxides produces Ti alkoxides which initiate the ring‐opening polymerization of __Ξ΅__‐caprolactone. A linear dependence of $\overline M \_{\rm n}$ on conversion, linear kinetics, low $\overline M \_{\rm w} /\overline M \