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Ring-opening polymerization of cyclic esters by pincer complexes derived from alkaline earth metals

✍ Scribed by Lamberti, Marina; Botta, Antonella; Mazzeo, Mina

Book ID
126139935
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
440 KB
Volume
28
Category
Article
ISSN
0268-2605

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Ring-opening polymerization of six-membe
Ring-opening polymerization of six-membered cyclic esters catalyzed by tetrahydroborate complexes of rare earth metals
✍ Yuushou Nakayama; Kenta Sasaki; Naoki Watanabe; Zhengguo Cai; Takeshi Shiono πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 341 KB

Catalytic behavior of tetrahydroborate complexes of rare earth metals, Ln(BH 4 ) 3 (THF) x (1: ), for ring-opening polymerization (ROP) of six-membered cyclic esters, d-valerolactone (VL) and D,L-lactide (D,L-LA), was studied. The controlled polymerization of VL with 1-6 proceeded in THF at 60 C. T