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Synthesis and Organocatalytic Ring-Opening Polymerization of Cyclic Esters Derived from l -Malic Acid

✍ Scribed by Pounder, Ryan J.; Dove, Andrew P.

Book ID: 125975277
Publisher: American Chemical Society
Year: 2010
Tongue: English
Weight: 511 KB
Volume: 11
Category: Article
ISSN: 1525-7797
DOI: 10.1021/bm1004355

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## Abstract **Summary:** The Ti^III^Cp~2~Cl‐catalyzed radical ring opening of epoxides produces Ti alkoxides which initiate the ring‐opening polymerization of __ε__‐caprolactone. A linear dependence of $\overline M \_{\rm n}$ on conversion, linear kinetics, low $\overline M \_{\rm w} /\overline M \