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Synthesis and Anionic Ring-Opening Polymerization Behavior of Amino Acid-Derived Cyclic Carbonates

✍ Scribed by Sanda, Fumio; Kamatani, Jun; Endo, Takeshi


Book ID
127257100
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
103 KB
Volume
34
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES


A novel observation in anionic ring-open
✍ Jyuhou Matsuo; Fumio Sanda; Takeshi Endo πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 581 KB

The anionic ring-opening polymerization of six-membered cyclic carbonates having aromatic substituents, 5-methyl-5-phenyl-l,3-dioxan-2-one (1) and 5,5-diphenyl-1,3-dioxan-2-one (2), was carried out. The anionic homopolymerization of 1 readily proceeds to afford the corresponding polycarbonate, while

Ring-opening polymerization of cyclic ca
✍ Jyuhou Matsuo; Shinji Nakano; Fumio Sanda; Takeshi Endo πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 180 KB πŸ‘ 2 views

Ring-opening reactions of 1,3-dioxepan-2-one (1) and 1,3-dioxan-2-one (2) with several alcohols were examined. The reactions proceeded without trifluoroacetic acid (TFA) in low conversions, while they proceeded smoothly with TFA to afford the ring-opened adducts and oligomers. Ring-opening polymeriz