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Wavelength effect in the photolysis of halogenated ketones

โœ Scribed by Majer, J. R.; Olavesen, C.; Robb, J. C.


Book ID
127321734
Publisher
Royal Society of Chemistry
Year
1971
Weight
958 KB
Category
Article
ISSN
0045-6470

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Silicon isotope selection induced by magnetic isotope effects has been discovered in the photolysis of a silyl-containing ketone, PhCH,COSi( CH,),Ph. Silicon and carbon atom isotope selection occurs most effkiently when the photolysis is directed via the triplet radical-pair mechanism. This conclusi