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29Si magnetic isotope effects in the photolysis of silyl ketones

✍ Scribed by E.N. Step; V.F. Tarasov; A.L. Buchachenko

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 339 KB
Volume: 144
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87308-1

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✦ Synopsis

Silicon isotope selection induced by magnetic isotope effects has been discovered in the photolysis of a silyl-containing ketone, PhCH,COSi( CH,),Ph. Silicon and carbon atom isotope selection occurs most effkiently when the photolysis is directed via the triplet radical-pair mechanism. This conclusion is supported by CIDNP data.

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