The Photolysis of Halogenated Ketones
β Scribed by R. Bowles; J. R. Majer; J. C. Robb
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 65 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
The CIDEP of tert.butyl radicals during photolysis of di-tert.butyl ketone is analysed. Triplet and radical pair mechanism induce enhanced absorption and an E/A multiplet effect at the initiation stage. The F-pair polarization reflects S-To and S-T+ mixing due to a solvent dependent indirect exchang
Silicon isotope selection induced by magnetic isotope effects has been discovered in the photolysis of a silyl-containing ketone, PhCH,COSi( CH,),Ph. Silicon and carbon atom isotope selection occurs most effkiently when the photolysis is directed via the triplet radical-pair mechanism. This conclusi
## Abstract Previous studies have shown a significant OH yield from the reaction of RCO radicals (generated from the photolysis of corresponding ketone) with oxygen below total pressures of 200 Torr. The potential of these reactions as a source of OH radicals for flash photolytic kinetic studies is