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CIDEP during the photolysis of di-tert.butyl ketone

✍ Scribed by I. Carmichael; H. Paul

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
309 KB
Volume
67
Category
Article
ISSN
0009-2614

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✦ Synopsis

The CIDEP of tert.butyl radicals during photolysis of di-tert.butyl ketone is analysed. Triplet and radical pair mechanism induce enhanced absorption and an E/A multiplet effect at the initiation stage. The F-pair polarization reflects S-To and S-T+ mixing due to a solvent dependent indirect exchange interaction with J > 0.

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