## Crystal polarization energies are calculated at several temperatures for Xe. Kr. Ar and Ne and at several DreSSUreS for He. These results are used to estimate energies of the quasi-free electron staate from spktroscopic data for Xe, Kr. and Ar.
Wannier type impurity states in naphthalene-rare gas matrices and the energy of the quasi-free electron state
β Scribed by J.G. Angus; G.C. Morris
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 335 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Absorption and photoemission spectra of naphthalene-rare gas matrices are reported. Bands arising from transitions to the n = 2.3 impurity Wannier states of naphthalene in this condensed system are observed. From measured values of the molecular ionization potenti'al. threshold energy for electron photoemission and ionization potential of the naphthalene in the matrix. values of the medium polarization energy by the positive hole and the energy of the quasi-free excess electron in the medium are deduced.
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We provide an estimate of the energy of the bottom of the conduction band in golid Ne and consider the implications of this result for electron localization ia liquid Ne. The energy, Vo , of the quasi-free electron state [l] in the bottom of the conduction band and of a non-polar dense fluid or a si
Electronic excitations of XeMAr,%-clusters are studied using fluorescence excitation spectroscopy in the energy range of the electronic excitations of pure Xe. The composition of the clusters is changed between XeAr, and pure Xe,M by varying the concentration of Xe gas in a coexpansion between 0.01%