The equilibrium yields of three, high-pressure., gas-phase reactions were calculated using the virial equation of state, the modified equation of Redlich, and the Lewis fugacity rule. The results obtained do not differ very much from one another. However, when the calculations are performed for the
Viscous flow effects in the periodic pressure cycling of gas-phase catalytic reactions
β Scribed by Donald E. Cormack; Graig I. Beattie
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 429 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
AM-The prevtous study of Hamer and Cormack[l]. on the Increased effectrveness of gas phase catalybc reactions under condmons of oscillating external pressure, IS extended to include VISCOUS flow effects For this purpose, the full, time dependent equations of VISCOUS flow, drffuslon and chemical reachon for a first order, Isothermal reaction In a porous catalyst are solved numerIcally The mcluslon of VISCOUS effects results m a new dimensionless parameter, N It IS shown that In general the catalyst effectiveness factor IS smaller for smaller N It IS concluded, however, that even though VISCOUS effects might be very Important for extremely low permeabrbty catalysts, VISCOUS effects can be neglected for operatmg condmons such that N > 1 For one example cited ttus corresponds to a permeability of 0 2 mdhdarcy 1 lNTRoDucTloN In a recent pubhcatlon. Hamer and Cormack[l]
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