𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Viscous flow effects in the periodic pressure cycling of gas-phase catalytic reactions

✍ Scribed by Donald E. Cormack; Graig I. Beattie


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
429 KB
Volume
34
Category
Article
ISSN
0009-2509

No coin nor oath required. For personal study only.

✦ Synopsis


AM-The prevtous study of Hamer and Cormack[l]. on the Increased effectrveness of gas phase catalybc reactions under condmons of oscillating external pressure, IS extended to include VISCOUS flow effects For this purpose, the full, time dependent equations of VISCOUS flow, drffuslon and chemical reachon for a first order, Isothermal reaction In a porous catalyst are solved numerIcally The mcluslon of VISCOUS effects results m a new dimensionless parameter, N It IS shown that In general the catalyst effectiveness factor IS smaller for smaller N It IS concluded, however, that even though VISCOUS effects might be very Important for extremely low permeabrbty catalysts, VISCOUS effects can be neglected for operatmg condmons such that N > 1 For one example cited ttus corresponds to a permeability of 0 2 mdhdarcy 1 lNTRoDucTloN In a recent pubhcatlon. Hamer and Cormack[l]


πŸ“œ SIMILAR VOLUMES


The solvent effect in chemical equilibri
✍ L.D. Sortland; J.M. Prausnitz πŸ“‚ Article πŸ“… 1965 πŸ› Elsevier Science 🌐 English βš– 333 KB

The equilibrium yields of three, high-pressure., gas-phase reactions were calculated using the virial equation of state, the modified equation of Redlich, and the Lewis fugacity rule. The results obtained do not differ very much from one another. However, when the calculations are performed for the

Effects of sudden pressure changes in th
✍ Dipl.-Ing. Norbert Wiese; Prof. Dr.-Ing. JΓΆrg Schwedes πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 511 KB

The variation in the behaviour of bulk solids as a result of sudden pressure changes in the surrounding gas phase is of interest in the application of lock hoppers for transfer of bulk solids into pressure vessels. By using such sluice systems, problems occur due to consolidation of the pressurized

Stopped-flow studies of the mechanisms o
✍ John T. Herron; Robert E. Huie πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 894 KB

The reactions of ozone with propene and isobutene have been studied in the gas phase at 298'K and 530 Pa (4 torr) using a stopped-flow reactor coupled to a photoionization mass spectrometer. Reactant and product concentrations were followed as a function of reaction time. The major reaction products

Different Catalytic Effects of a Single
✍ Josep M. Anglada; Javier Gonzalez πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 762 KB

## Abstract __The effect of a single water molecule on the reaction mechanism of the gas‐phase reaction between formic acid and the hydroxyl radical was investigated with high‐level quantum mechanical calculations using DFT–B3LYP, MP2 and CCSD(T) theoretical approaches in concert with the 6‐311+G(2