✦ LIBER ✦

The solvent effect in chemical equilibria of high-pressure, gas-phase reactions

✍ Scribed by L.D. Sortland; J.M. Prausnitz

Publisher: Elsevier Science
Year: 1965
Tongue: English
Weight: 333 KB
Volume: 20
Category: Article
ISSN: 0009-2509
DOI: 10.1016/0009-2509(65)80077-x

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✦ Synopsis

The equilibrium yields of three, high-pressure., gas-phase reactions were calculated using the virial equation of state, the modified equation of Redlich, and the Lewis fugacity rule. The results obtained do not differ very much from one another. However, when the calculations are performed for the case where the reactions proceed in the presence of a (chemically) inert gaseous solvent, the yields computed by the equations of state are very much different from those calculated by the Lewis rule. If a suitable gaseous solvent is used, the equilibrium yield can be significantly increased over that obtained in the absence of any solvent.

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