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Vinyl Radicals. Stereoselectivity in Hydrogen Atom Transfer to Equilibrated Isomeric Vinyl Radicals1

โœ Scribed by Singer, Lawrence A.; Kong, Noland P.

Book ID
115512698
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
854 KB
Volume
88
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Stereoselective hydrogenation of ฮฑ-sulfi
Stereoselective hydrogenation of ฮฑ-sulfinyl radical generated from alkyl radical addition to ฮฑ-(1-hydroxyethyl)vinyl sulfoxide
โœ Nobuyuki Mase; Shutaro Wake; Yoshihiko Watanabe; Takeshi Toru ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 260 KB

The reaction of (2S,Ss)-0t-(I-hydroxyethyl)vinyl sulfoxide with alkyl radicals and tributyltin hydride gave the addition-hydrogenation products with high diastereoselectivity, whereas (2R,Ss)-~-( Ihydroxyethyl)vinyl sulfoxide gave no products under similar conditions. An important role of intramolec