𝔖 Bobbio Scriptorium
✦   LIBER   ✦

(1,2)-Hydrogen shift in monovalent carbon compounds: the methylcarbyne-vinyl radical isomerization

✍ Scribed by Nielsen, Ida M. B.; Janssen, Curtis L.; Burton, Neil A.; Schaefer, Henry F.

Book ID
120082912
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
628 KB
Volume
96
Category
Article
ISSN
0022-3654

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Evidence for a 1,2 Shift of a Hydrogen A
Evidence for a 1,2 Shift of a Hydrogen Atom in a Radical Intermediate of the Methylmalonyl-CoA Mutase Reaction
✍ Meinrad Kunz; JΓ nos RΓ©tey πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 100 KB

An excellent substrate of methylmalonyl-CoA mutase, methylmalonyl-carba-(dethia) coenzyme A (methylmalonyl-CH(2)-CoA), was synthesized by a chemoenzymatic method and its alpha-proton was exchanged with deuterium by long-term incubation in deuterium oxide at pH 6.9. After addition of highly purified

Chain transfer by addition-fragmentation
Chain transfer by addition-fragmentation mechanism. VII. Radical polymerization of vinyl monomers in the presence of ethyl 2-[1-(trimethylsilylperoxy)ethyl]propenoate and related compounds
✍ Daniel Colombani; Isabelle Beliard; Philippe Chaumont πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 781 KB

Ethyl 2-[ 1-(trimethylsilylperoxy)ethyl]propenoate 1, ethyl 2-[ 1-(dimethylvinylsilylperoxy)ethyllpropenoate 2, ethyl 2-[ 1-( l-(2-ethoxycarbonyl-l-methyl-2-propenylperoxysilyl)-l-methylethylperoxy)ethyl]propenoate 3, and 2-phenyl-2-trimethylsilylperoxypropane 4 were synthesized and added to the fre