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cis-trans Isomerization in Vinyl Radicals. Gas Phase Radical-Chain Addition of Hydrogen Bromide to Propyne

✍ Scribed by Skell, Philip S.; Allen, Richard G.


Book ID
126482224
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
201 KB
Volume
86
Category
Article
ISSN
0002-7863

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Addition of hot hydrogen atoms to 1-bute
✍ Janusz GawΕ‚owski; Jan Niedzielski πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 619 KB

## Abstract The reaction of hot hydrogen atoms originating from 253.7‐ and 228.8‐nm photolyses of hydrogen sulfide with 1‐butene was investigated. Of the hydrogen atoms undergoing addition a substantial part undergoes it in a first collision (37 and 48% at 253.7 and 228.8 nm, respectively) yielding