Vilsmeier reagent for a high yield conversion of aldoximes to nitriles
β Scribed by Jean-Pierre Dulcere
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 108 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Vilsmeier reagents I have previously been used almost exclusively for formylation (I).
More recently they were shown to be useful reagents in organic synthesis.
π SIMILAR VOLUMES
Dehydration of Aldoximes to Nitriles Using a Polymeric Reagent. -Polyvinylpyrrolidone-SOCl 2 -mediated dehydration of aldoximes (I) proceeds rapidly under mild conditions to furnish the corresponding nitriles in high yields. The reaction tolerates aliphatic, olefinic, heteroaromatic, and aromatic al
## Abstract For Abstract see ChemInform Abstract in Full Text.
Diphenylphosphinodithioic acid is a reagent useful for a sequence effecting the hydrolysis of nitriles under mild conditions. Of all functional groups at the acyl level of oxidation, nitriles are the most resistant to reaction. The poor electrophilicity of the carbon combined with the weak basicity
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v