A Conversion of Aldoximes to Nitriles Using Dabco/Thionyl Chloride Complex.
β Scribed by F. Kazemi; A. R. Kiasat
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 76 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Dehydration of Aldoximes to Nitriles Using a Polymeric Reagent. -Polyvinylpyrrolidone-SOCl 2 -mediated dehydration of aldoximes (I) proceeds rapidly under mild conditions to furnish the corresponding nitriles in high yields. The reaction tolerates aliphatic, olefinic, heteroaromatic, and aromatic al