## Abstract The magnitudes of ^13^C๏ฃฟ^14^N coupling constants have been measured in 12 rigid or anancomeric (biased) tetraalkylammonium iodides. The oneโbond coupling is typical for the degree of substitution of the carbon atom and the geminal coupling is very small. Vicinal couplings depend on the
Vicinal Exocyclic Coupling and Constitutional Problems
โ Scribed by M. Anteunis
- Book ID
- 101761342
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 206 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0037-9646
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๐ SIMILAR VOLUMES
## Abstract Carbonโcarbon coupling constants in monoterpene hydrocarbons (3โcarene, ฮฑโpinene and camphene) were investigated. A selective version of the INADEQUATE experiment was used for measurements of the longโrange __^n^J__(CC) values. The dependence of the vicinal ^13^C๏ฃฟ^13^C coupling constant
## Abstract The ^13^C๏ฃฟ^13^C vicinal coupling constants of cyclic sulphonium cations, with the labelled carbon bound to the positively charged sulphur atom, cannotbe related to the dihedral angle ฯ by a Karplus type correlation.
## Abstract Values of long range ^13^CH coupling through the double bond in a number of isopropenyl compounds are reported. There is evidence that substituent dependence of ^3^__J__(CH) is not related linearly to that of H๏ฃฟH couplings in vinyl compounds. The ratio of ^3^__J__(CH) to ^3^__J__(HH) in