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Vicinal 13C13C coupling constants in bicyclic monoterpenes

✍ Scribed by Aleksej Y U. Denisov; Aleksej V. Tkachev; Viktor I. Mamatyuk

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
377 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon–carbon coupling constants in monoterpene hydrocarbons (3‐carene, α‐pinene and camphene) were investigated. A selective version of the INADEQUATE experiment was used for measurements of the long‐range ^n^J(CC) values. The dependence of the vicinal ^13^C^13^C coupling constants on the dihedral angles and the types of molecular framework involved within the direct coupling path is discussed. The configuration of a heteroatomic derivative from α‐pinene was determined from its ^3^J(CC) values.

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