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Vibration–Vibration energy exchange between N2O and CO

✍ Scribed by Jerry W. Suitor; W. C. Kuby

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
542 KB
Volume
7
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The temperature dependence of the vibration–vibration energy transfer between the v~3~ mode of N~2~O and the first vibrational level of CO was determined over a range of 780 to 1400°K using a shock tube. Several mixtures of CO‐N~2~O were tested, diluted in 95% Ar. The Landau–Teller plot of the vibration–vibration relaxation times has a least squares line of
where pτvv is in atm ˙μsec and T in °K. The measured kinetic reaction was determined to be
The transfer probabilities for this process were found to vary directly with temperature.

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