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The temperature dependence of vibration–vibration energy exchange between CO and COS

✍ Scribed by Dennis C. Richman; Miriam Lev-on; Roger C. Millikan

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
237 KB
Volume
7
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The present study reports the measurement of the V–V energy transfer rates for the CO*COS system in the temperature range of 195 to 370°K. The measured rates exhibit a slight inverse temperature dependence. The experimental results are compared to prediction based on a model of long‐range dipole–dipole interactions between colliding molecules. The effect of single quantum rotational transitions is compared to that of multiquantum rotational transitions.

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