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The vibrational spectra and normal co-ordinate analysis of NaOX (X = H or D)

✍ Scribed by Isao Kanesaka; Masaaki Tsuchida; Kiyoyasu Kawai

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 307 KB
Volume: 13
Category: Article
ISSN: 0377-0486
DOI: 10.1002/jrs.1250130309

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✦ Synopsis

Abstract

The vibrational spectra of NaOX (X = H or D) at room temperature and 77 K are reported. A normal co‐ordinate analysis has been carried out to assign the observed bands on the basis of the valence force field. The force constants were adjusted by considering a bond distance and reproduce well the observed frequencies. In the dispersion relations on k~2~ and k~x~ the librational modes were found to be insensitive to k, whereas the translational modes except for the A~1g~ and B~1u~ modes vary considerably with k. Some bands were assigned to the combination band between a fundamental and an acoustic mode.

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