𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vibration–vibration energy exchange between 15N14NO and CO

✍ Scribed by Jerry W. Suitor; W. C. Kuby

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
186 KB
Volume
9
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The temperature dependence of the vibration–vibration energy transfer between the v~3~ mode of ^15^N^14^NO and the first vibrational level of CO was determined over a range of 680 to 1300°K using a shock tube. Several mixtures of ^15^N^14^NOCO were tested, diluted in 95% Ar. The resulting exothermic transfer probabilities for the reaction,

are compared to previous work on N~2~O—CO. The results for ^15^N^14^NOCO exhibit a more pronounced direct temperature dependence than for N~2~O—CO even though the process has a closer resonance (Δ__E__ = 59 cm^−1^ for ^15^N^14^NOCO and Δ__E__ = 81 cm^−1^ for N~2~OCO).

📜 SIMILAR VOLUMES

The temperature dependence of vibration–
The temperature dependence of vibration–vibration energy exchange between CO and COS
✍ Dennis C. Richman; Miriam Lev-on; Roger C. Millikan 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB

## Abstract The present study reports the measurement of the V–V energy transfer rates for the CO\*COS system in the temperature range of 195 to 370°K. The measured rates exhibit a slight inverse temperature dependence. The experimental results are compared to prediction based on a model of long‐r

Room temperature spectroscopic investiga
Room temperature spectroscopic investigations of K14NO3 , K15NO3 , K14N16O3−x18Ox and a 1:1 mixture of K14NO3 and K15NO3: intermolecular coupling revealed in the vibrational spectra
✍ Taposh Chakraborty; P. K. Bajpai; A. L. Verma 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB 👁 1 views

The di †use reÑectance Fourier transform IR (DRIFT) and Raman spectra for microcrystalline K14NO 3 , and a 1 : 1 mixture of and were measured at room temperature. K15NO 3 new assignment for the observed factor group split components of the asymmetric N-O stretching mode and infrared evidence for th