Vibrationally Mediated Photodissociation of C 2 H 4+†
✍ Scribed by Kim, Myung Hwa; Leskiw, Brian D.; Shen, Lei; Suits, Arthur G.
- Book ID
- 126136956
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 791 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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A reinvestigation of the vibrationaBy mediated photodissociation spectrum of the 3rd OH stretching overtone (411cu) of jetcooled HsO,, first observed by Crim and co-workers, reveals anomalous double resonance spectral intensities compared with those observed via hi&-resolution absorption spectroscop
Photofragment vector correlations for photofragments generated through vibrationally mediated photodissociation have been measured for the first time. The results obtained for HzOz, dissociated via the third O-H overtone state, 4u,\_,, implicate torsional motion in the intermediate state as a contri