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Vibrational study of ionic association in aprotic solvents. 8. Copper(I) thiocyanate in soft donor solvents

✍ Scribed by Rannou, J.; Chabanel, M.


Book ID
127261511
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
313 KB
Volume
24
Category
Article
ISSN
0020-1669

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Vibrational study of ionic association i
✍ Corinne Le Borgne; Martial Chabanel πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 557 KB

Complexes between alkaline-earth-metal ions M\*' and cyanate OCN' in aprotic solvents are studied by infrared spectrometry in the v(CN) region (2150-2250 cm-'). In dimethylsulphoxide (DMSO) and hexamethylphosphotriamide (HMPT) isocyanate MNCO ion pairs exhibit a specific v(CN) band while M(NCO)z spe