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Vibrational study of ionic association in aprotic solvents. Part 12. Isothiocyanate M(NCS) complexes of non-transition-metal ions

โœ Scribed by Chabanel, Martial; Bencheikh, Abderrahim; Puchalska, Danuta

Book ID
121188717
Publisher
The Royal Society of Chemistry
Year
1989
Tongue
English
Weight
742 KB
Volume
11
Category
Article
ISSN
1472-7773

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Vibrational study of ionic association i
Vibrational study of ionic association in polar aprotic solvents. Isocyanate complexes of non-transition-metal ions
โœ Corinne Le Borgne; Martial Chabanel ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 557 KB

Complexes between alkaline-earth-metal ions M\*' and cyanate OCN' in aprotic solvents are studied by infrared spectrometry in the v(CN) region (2150-2250 cm-'). In dimethylsulphoxide (DMSO) and hexamethylphosphotriamide (HMPT) isocyanate MNCO ion pairs exhibit a specific v(CN) band while M(NCO)z spe