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Vibrational spectroscopic study of the peculiarities of intermolecular association in aprotic solvents

✍ Scribed by Igor S. Perelygin

Book ID
107995890
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
203 KB
Volume
116
Category
Article
ISSN
0378-3812

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✍ Corinne Le Borgne; Martial Chabanel πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 557 KB

Complexes between alkaline-earth-metal ions M\*' and cyanate OCN' in aprotic solvents are studied by infrared spectrometry in the v(CN) region (2150-2250 cm-'). In dimethylsulphoxide (DMSO) and hexamethylphosphotriamide (HMPT) isocyanate MNCO ion pairs exhibit a specific v(CN) band while M(NCO)z spe