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Vibrational relaxation of HCl in HCl/liquid xenon mixtures

✍ Scribed by J.Thomas Knudtson; Eric Weitz

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 806 KB
Volume: 104
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85307-5

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✦ Synopsis

The vibrational relaxation of HCI in liquid xenon at -68°C has been studied. Vibrationally excited HCI is created following UV photolysis of HCI. The rate of relaxation of HCl as a function of HCl mole fraction in liquid xenon is the same as the correspondingrate forgas phaseHCIat -68°C. Similarly therate of relaxation of HCl in HCl-Xe collisions is in good agreement with the corresponding gas phase rate. These observations imply that the isolated binary collision model is valid for this system.

* Work performed at Northwestern University-* Alfred P. Sloan Fellow 1978-1982. gases which may have extensions to a variety of other appropriate sysrems.

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