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Vibrational relaxation of hydrogen chloride molecules: HCl(ν) + HCl(0) → HCl(ν - 1) + HCl(0)

✍ Scribed by H.K. Shin

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
678 KB
Volume
98
Category
Article
ISSN
0009-2614

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✦ Synopsis

HCI(u) -I-HCI(0) + HCI( u -1) + HCI(0) Rcceibed 22 April 1983 The deexitdtion of hydrogen chloride molecules tllroqh HCI(u) + HCI(0) + HCI(u -1) + HCI(0) has been studied by USC of a model that is bJsed on the trmsfer of vibrational enerey to rotation. The contribution of transbtion to vibrationto-rotation energy transfer is included in the model. Deelcitation probabilities obtained by summing the V-R and V-RJ conrributions are shown to rise rapidly with increasirq V, and both the magnitude and u dependence of probabilities are found to be in reasonable ;~preernenr with observed data.

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