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The vibrational relaxation of HCl(1) by Cl and Br atoms

✍ Scribed by Z. Karny; B. Katz

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 269 KB
Volume: 38
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85178-0

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✦ Synopsis

The vibrational relaxation of HCl(u= 1) by chlorine and bromine atoms has been me:lsured at 295 K by :I discharge fbW SySti%l using the resonance fluorescence method to dctcct the hiIlogen atom concentration, combined with laser induced tkorescencc. T&c rnessured rate comtants arc: K(HCI-Cl) = (7.0 5 1.5) X lo-l2 cm3 n~olcc~lc-~ s-l, K(IICI--I3r) = (2.6 * 0.5) x 1 I?-'3 an3 rnoteculc-* S--I.

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