The vibrational relaxation of ozone by helium atoms
β Scribed by D.C. Clary
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 358 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
An ~b mhio. quxuum-nwch3nlrxl nwhod IS used IO compute rxc cocfiiicisnls ior the ubral~onsl rclau~l~on olozonc III ihrccdlmcnslonal colbslons WII~ bcbum atoms Good qxeemcnt 15 obr~mcd bctwccn tbr c.~lcul~tcd and qwmwlsl MC cocfiicwnts Tar the process Ilc -F @(OlO) -Ilc + 03(000)
π SIMILAR VOLUMES
The relaxation of 03(001) by p-and n-Hz was measured over the temperature range 167-424 K. n-Hz quenched ozone more efficiently, with the difference between rate constants increasing with temperature. These observations are explained by a near-resonant V-R process, in agreement with the Sharma-&au t
The vibrational relasation time for COz(v3) + O(3P) has been mcasurcd by Inscr fluorescence. The observed value, pCo2,0 = 0.21 \* 0.04 fiscc, is an order of mqniludc lower than the relaxation time for self-collisions.
## Abstract The rate of vibrational relaxation of HF(__v__ = 1) by F atoms has been calculated using quasiβclassical trajectory techniques. An attempt has been made to account for the effects of multiple potential energy surfaces on the vibrational relaxation efficiency within the electronically ad
The vibrational relaxation of HCl(u= 1) by chlorine and bromine atoms has been me:lsured at 295 K by :I discharge fbW SySti%l using the resonance fluorescence method to dctcct the hiIlogen atom concentration, combined with laser induced tkorescencc. T&c rnessured rate comtants arc: K(HCI-Cl) = (7.0