An ~b mhio. quxuum-nwch3nlrxl nwhod IS used IO compute rxc cocfiiicisnls ior the ubral~onsl rclau~l~on olozonc III ihrccdlmcnslonal colbslons WII~ bcbum atoms Good qxeemcnt 15 obr~mcd bctwccn tbr c.~lcul~tcd and qwmwlsl MC cocfiicwnts Tar the process Ilc -F @(OlO) -Ilc + 03(000)
Vibrational relaxation by metal atoms
β Scribed by Edward R. Fisher; Geoffrey K. Smith
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 264 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The vibrational relasation time for COz(v3) + O(3P) has been mcasurcd by Inscr fluorescence. The observed value, pCo2,0 = 0.21 \* 0.04 fiscc, is an order of mqniludc lower than the relaxation time for self-collisions.
## Abstract The rate of vibrational relaxation of HF(__v__ = 1) by F atoms has been calculated using quasiβclassical trajectory techniques. An attempt has been made to account for the effects of multiple potential energy surfaces on the vibrational relaxation efficiency within the electronically ad
The vibrational relaxation of HCl(u= 1) by chlorine and bromine atoms has been me:lsured at 295 K by :I discharge fbW SySti%l using the resonance fluorescence method to dctcct the hiIlogen atom concentration, combined with laser induced tkorescencc. T&c rnessured rate comtants arc: K(HCI-Cl) = (7.0
A two-laser, pump-probe arrangement has been used to measure room-temperature rate constants for the collision-induced relaxation of NO(v ~ 2, 3) by O atoms. The rate constants ko(o) are equal to (2.2 + 0.2) Γ 10-~t and (2.5 + 0.3) x 10 -11 cm 3 s -1 for v = 2 and 3, respectively. These values are s