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Detection of Cl atoms and HCl molecules by resonantly enhanced multiphoton ionization

โœ Scribed by Sivaram Arepalli; Nathan Presser; Daniel Robie; Robert J. Gordon


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
448 KB
Volume
118
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Resonantly enhanced multiphoton ionization has been used to detect cI(3~'P.j'~) and Ci*(3p2PF'> via the pumping of two-photon-allowed nansitians rn the wavelength region of 230-245 nm. The precursors used to generate Cl atoms were CH,CI,, CF,CI, and Ccl,. Two-photon-allowed rransikions of HQ and DCI molecules were also observed in this region, with a dclauon scnsitiwry ol belter than 10" molecules/c&.


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An order of magnitude enhancement of the XeCl(B,C) formation rate constants was observed for the 300 K reactions of Xe( 6p[ l/2] 0 and [ 3/2]\*) atoms with CF&l, CF& and CF,HCl, relative to the reactions of Xe( 6s, 3P2) atoms. Similar large XeCl( B,C) formation enhancement factors were found for rea