Vibrational l-type doubling and l-type resonance in linear polyatomic molecules
β Scribed by Gilbert Amat; Harald H. Nielsen
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- English
- Weight
- 641 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
Direct /-type doubling transitions in the 06 = 1 state of CF379Br, CF3SIBr and CF3I have been observed using the technique of Fourier transform microwave spectroscopy in the range 4.5-8 GHz. The transitions covered a range of J values from 38-47 for both isotopomers of CF3Br and from 40-51 for CFaI.
A high resolution spectroscopic study of a fast N,O+ beam reveals an l-type resonance in the 020 level of the A \*X + state. A value of 1.39 cm-' for the anharmonicity parameter g2, is obtained from a rotational analysis of the 020 \*A-O20 % transition. This is the first determination of the constan