The relauon between molecular structure and efticrcncy of wbratronal energy transfer between gas molecules rnd J surface has been ektcndcd to the pau cycloprop;lne/cyclopropanc~6 The latter ts less ciiictent to energy loss. as corresponds to Its greater wbratronal clgcnstatc dcnsrty Convcrscly, the
Vibrational energy transfer in cyclopropane (C3H6)
✍ Scribed by J.D. Chen; J. Häger; W. Krieger
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 306 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Recelrcd 30 April 1982, in Iii1 form 11 June I%? lnirved laser-Induced lluorescence mcasuremen~s of viiraaond rdaxauon in cyclopropone are presented. Following laser eua:ahon of the CH-siretch nbratxons vg and vg lime-dependent nuorescence signals from q. and u,/vll were recorded. Activation and dcachvation rate constants for C3H6-C3H6 colhions were found for v,o and v7/uII. A sunplircd model for the nbntional relaxauon of cyclopropane is &cussed.
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