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Vibrational energy transfer in CD3F

✍ Scribed by L.A. Gamss; B.H. Kohn; A.M. Ronn; G.W. Flynn

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 631 KB
Volume: 41
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85384-5

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✦ Synopsis

Infrared fluorescence from the IQ and v4 vibrational levels has been observed in CDaF following excitation by a 10.6 fi Q-switch COa laser. The exponential deactivation rate constant has been found to be 0.44 ms-r torr-t for the pure gas.

The rate constants for deactivation by the rare gases have also been measured and vary between 3.26 and 0.025 ms-* torr-'. A lower limit of 500 ms-* torr-' is set on the vt , ~4 activation rate. A discussion of these results is presented based on the energy level scheme of CDaF and existing V-T/R theories.

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